科研项目: 1. 新型边缘硼氮杂稠环芳烃衍生物的设计、合成及物理化学性质研究(22061041) ,国家自然科学基金,主持人 2. 新型硼氮杂纳米石墨烯分子的设计、合成及性质研究(2023-YBGY-430), 陕西省重点研发项目,主持人 3. 低价铬、铁及钴催化体系的构建及用于稠环芳烃的可控性去芳构化(2020JQ-789) ,陕西省科技厅项目,主持人 4. 新型石墨烯纳米材料的设计、合成及性质研究(CXY-2022-185), 榆林市重点产业链项目,主持人 5. 基于苯并菲骨架构建碗状氮杂多环芳烃类化合物的合成及其性质研究(11JK0563) ,陕西省教育厅项目,主持人 6. 新型含硫有机光电材料的构建及其合成工艺研究(16JS122) ,陕西省教育厅项目,主持人 7. 基于mannich 反应构建新型有机光电材料及其性质研究(2015KG-01),延安市科技局项目,主持人 学术论文: 1. Bo Han, Pengchen Ma, Xuefeng Cong, Hui Chen, Xiaoming Zeng*. Chromium- and Cobalt-Catalyzed, Regiocontrolled Hydrogenation of Polycyclic Aromatic Hydrocarbons: A Combined Experimental and Theoretical Study. J. Am. Chem. Soc., 2019, 141, 9018-9026. 2. Bo Han,* Hongmei Jiao, Rong Chen, Yuqi Zhang*. Jijiang Wang. Chemoselective Reduction of Imines and Azobenzenes Catalyzed by Silver N-heterocyclic Carbene Complexes. Org. Chem. Front., 2023, 10, 2287-2293. 3. Hui Zhou, Hongmei Jiao, Xing Lu, Yuanyuan Gao, Zhiqiang Ren, Haojie Ma, Yuqi Zhang, Bo Han*. Chemoselective Transfer Hydrogenation of Nitroarenes with Ammonia Borane Catalyzed by Copper N-heterocyclic Carbene Complexes. Chin. J. Chem., 2024, 42, 1721-1726. 4. Hui Zhou, Nana Wei, Zhiqiang Ren, Haojie Ma, Yuqi Zhang, Bo Han*. Reductive Synthesis of Alcohols from Carboxylic Acids and Esters Catalyzed by a Copper N-heterocyclic Carbene Complex. Chin. J. Chem., 2024, 10.1002/cjoc.202400766 5. Junfa Wei*, Bo Han, Qiang Guo, Xianying Shi, Wenliang Wang, and Ni Wei. 1,5,9-Triazacoronenes: A Family of Polycyclic Heteroarenes Synthesized by a Threefold Pictet– Spengler Reaction. Angew. Chem. Int. Ed., 2010, 49, 8209–8213. 6. Hongmei Jiao,Hui Zhou, Xing Lu,Yuanyuan Gao, Xueyan Hou, Yuqi Zhang, Bo Han*,Silver-Catalyzed Selectively Reduction of the C=C Bond of an α,β-Unsaturated Ketones in Water. Scientia Sinica Chimica, 2024, 54, 1099–1106. 7. Hongmei Jiao, Rong Chen, Miaomiao Zhang, Wanzhen Guo, Yuanyuan Gao, Yuqi Zhang, Bo Han*. Silver-Catalyzed Reduction of Nitro to Amines in Water. Scientia Sinica Chimica, 2024, 54, 260–266. 8. Miaomiao Zhang, Hongmei Jiao, Rong Chen, Haojie Ma, Ran Li, Jijiang Wang, Bo Han*,Yuqi Zhang*. Zn-Catalyzed Regioselective and Chemoselective Reduction of Aldehydes, Ketones and Imines. Int. J. Mol. Sci., 2022, 23, 12679. 9. Bo Han*,Miaomiao Zhang, Hongmei Jiao, Rong Chen, Haojie Ma, Ran Li, Jijiang Wang, Yuqi Zhang*. Regioselective Hydrogenation of Polycyclic Aromatic Hydrocarbons and Olefins Catalyzed by Magnesium-Activated Chromium Complexes. ChemistrySelect, 2022,7, e202200776. 10. Miaomiao Zhang, Bo Han*, Haojie Ma, Jijiang Wang, Yuqi Zhang*.Hydrosilanes as Hydrogen Source: Iridium-Catalyzed Hydrogenation of N-Heteroarenes. Chin. J. Org.Chem., 2022, 4, 1170–1178. 11. Bo Han*,Feifei Liu,Yuqi Zhang, Qiao Wang, Rongxuan Ma, Hong Guo. Condensation Reactions between Aldehydes and β-Naphthol Catalyzed by Silicotungstic Acid. Chin. J. Org. Chem., 2012, 32, 1121–1125. 12. Bo Han*, Miaomiao Zhang, Hongmei Jiao, Haojie Ma,Jijiang Wang, Yuqi Zhang*. Ligand-Enabled and Magnesium-Activated Hydrogenation with Earth-Abundant Cobalt Catalysts.RSC Advances,2021, 11, 39934–39939. 13. Heng Li,‡ Bo Han,‡ Haojie Ma, Ran Li, Xueyan Hou, Yuqi Zhang,* Ji-Jiang Wang. A “turn-on” inverse opal photonic crystal fluorescent sensing film for detection of cysteine and its bioimaging of living cells. Microchimica Acta, 2023, 190, 49. 14. Miaomiao Zhang, Rong Chen, Hongmei Jiao, Haojie Ma, Bo Han*,Yuqi Zhang, Jijiang Wang. MgCl2-Catalyzed Chemoselective Reduction of Aldehydes, Ketones and Imines. Chin. J. Org. Chem., 2023, 43, 1462–1471. 15. Xiaokang Lu,‡ Bo Han,‡ Deyilei Wei, Mingzhu Chu, Haojie Ma, Ran Li, Xueyan Hou, Yuqi Zhang,*Ji-Jiang Wang. A fluorescence-enhanced inverse opal sensing film for multi-sources detection of formaldehyde. Food Science and Human Wellness. 2024, DOI: 10.26599/FSHW.2024.9250115. 获 奖: 1. 2024 年陕西省化学优秀青年奖 2. 2024 年4001百老汇会员登录优秀硕士学位论文指导教师 3. 2023 年4001百老汇会员登录优秀硕士学位论文指导教师 4. 2020 年4001百老汇会员登录课堂教学创新大赛“教授风采 ”赛道理科组二等奖 专 利: 1. 韩波, 焦红梅, 周慧, 张玉琦. 一种催化亚胺类化合物还原制备仲胺类化合物的方法. 中国发明专利, ZL202211443994.5 2. 韩波, 张苗苗, 焦红梅, 马豪杰, 张玉琦. 一种非氢气参与选择性催化氢化喹啉类化合 物合成四氢喹啉类化合物的方法. 中国发明专利,ZL202111201427.4 3. 韩波, 张苗苗, 张玉琦. 一种非氢气参与选择性催化氢化芳香杂环类化合物的方法, 中国发明专利,ZL202110591481.8 4. 韩波, 张苗苗, 焦红梅, 陈荣, 张玉琦. 一种基于醋酸锌催化羰基还原制备醇类化合物 的方法. 中国发明专利,ZL202210050251.5 5. 韩波, 张苗苗, 焦红梅, 马豪杰, 张玉琦. 一种基于镁活化配体促进的铬催化稠环芳烃 及烯烃的区域选择性氢化方法. 中国发明专利,CN202111175005.4 6. 韩波, 周慧, 韦娜娜, 郭婉真, 鲁星, 张玉琦. 一种 N-杂环卡宾铜络合物均相催化还原 羧酸衍生物制备伯醇的方法. 中国发明专利,CN202411026535.6 7. 韩波, 周慧, 韦娜娜, 焦红梅, 鲁星, 任志强, 张玉琦. 一种 N-杂环卡宾铜络合物催化还原硝基芳烃制备芳伯胺的方法. 中国发明专利,CN202311316826.4 8. 韩波, 陈荣, 焦红梅, 张苗苗, 张玉琦. 一种三氟甲烷磺酸银催化还原硝基芳烃制备芳伯胺的方法. 中国发明专利,CN202310862497.7 9. 曾小明, 韩波, 罗美明. 基于钴盐选择性催化氢化多环芳烃的方法, 中国发明专利, ZL201710396265. 1. 10. 曾小明, 韩波, 罗美明. 一种铬盐/甲基溴化镁选择性催化氢化多环芳烃的方法, 中国发 明专利, ZL201710396279.3. 11. 魏俊发, 韩波, 李明, 张朋, 韩亚军, 高艳妮, 常健, 石先莹, 王文亮, 魏妮. 均三氮杂蒄化 合物及其合成方法和应用, 中国发明专利, ZL201010282723.7. |